A multi-faceted approach to probe organic phase composition in TODGA systems with 1-alcohol phase modifiers.

ABSTRACT: The effect of varying 1-alcohol alkyl chain length on extraction of lanthanides (Lns), H₂O, and H⁺ was studied with tetraoctyl diglycolamide (TODGA) via solvent extraction coupled with FT-IR investigations. This multi-faceted approach provided understanding regarding the relationship between extracted Lns, H₂O and H⁺, 1-alcohol volume fraction, and 1-alcohol alkyl chain length. Under acidic conditions there is competition with 1-alcohols and their ability to solubilize aggregates and incidentally induce third phase formation by increasing the extraction of H₂O. At low 1-alcohol concentrations (5 vol%), the trend for 1-alcohol alkyl lengths in solubilizing the aggregates is 1-hexanol > 1-octanol > 1-decanol. Shorter alkyl chains

SUBMITTER: Peroutka AA 

PROVIDER: S-EPMC9939940 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature