Reaction of an Ion and a Free Radical near 0 K: He⁺ + NO → He + N⁺ + O.

ABSTRACT: The reactions between ions and free radicals are among the fastest chemical reactions. They are predicted to proceed with large rates, even near 0 K, but so far, this prediction has not been verified experimentally. We report on measurements of the rate coefficient of the reaction between the ion He⁺ and the free radical NO at collision energies in the range between 0 and ∼ k_B·10 K. To avoid heating of the ions by stray electric fields, the reaction is observed within the large orbit of a Rydberg electron of principal quantum number n ≥ 30, which shields the ion from external electric fields without affecting the reaction. Low collision energies are reached by merging a supersonic beam of He Rydberg atoms with a supersonic beam of NO molecules and adjust

SUBMITTER: Zhelyazkova V 

PROVIDER: S-EPMC9940198 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature