Unravelling and overcoming the challenges in the electrocatalytic reduction of fructose to sorbitol.

ABSTRACT: In this work, we present a comprehensive study of the electrocatalytic reduction of fructose to sorbitol and mannitol, in a mild alkaline medium (pH = 11.3), with a Cu wire as the cathode. Particular attention was paid to the reaction mechanism, investigated by linear sweep voltammetry (LSV) and chronopotentiometry (CP) coupled with high-pressure liquid chromatography (HPLC). The initial results of our study showed that at the potential where the fructose reduction reaction (FRR) is achieved, competition with the hydrogen evolution reaction (HER) tends to occur, thus limiting the Faradaic efficiency towards the FRR. Moreover, products of chemical conversions were also observed in the liquid electrolyte, originating from the isomerisation of fructose to glucose and mannose and degradation r

SUBMITTER: Creus J 

PROVIDER: S-EPMC9940304 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature