Ligand-to-Copper Charge-Transfer-Enabled C-H Sulfoximination of Arenes.

ABSTRACT: Herein, we report a photoinduced sulfoximine-to-copper charge-transfer-enabled generation of sulfoximinyl radicals directly from NH-sulfoximines for C-H sulfoximination of arenes via radical addition. Through copper-LMCT, N-arylation of NH-sulfoximines was achieved for the first time using arenes of different electronic structures as the aryl donors.

SUBMITTER: Su W 

PROVIDER: S-EPMC9942232 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature