Discrete Singular Metallophilic Interaction in Stable Large 12-Membered Binuclear Silver and Gold Metallamacrocycles of Amido-Functionalized Imidazole and 1,2,4-Triazole-Derived N-Heterocyclic Carbenes.

ABSTRACT: Metallophilic interactions were observed in four pairs of 12-membered metallamacrocyclic silver and gold complexes of imidazole-derived N-heterocyclic carbenes (NHCs), [1-(R¹)-3-N-(2,6-di-(R²)-phenylacetamido)-imidazol-2-ylidene]₂M₂ [R¹ = p-MeC₆H₄, R² = Me, M = Ag (1b) and Au (1c); R¹ = Me, R² = i-Pr, M = Ag (2b) and Au (2c); R¹ = Et, R² = i-Pr, M = Ag (3b) and Au (3c)], and a 1,2,4-triazole-derived N-heterocyclic carbene (NHC), [1-(i-Pr)-4-N-(2,6-di-(i-Pr)-phenylacetamido)-1,2,4-triazol-2-ylidene]₂M₂ [M = Ag (4b) and Au (4c)]. The X-ray diffraction

SUBMITTER: Prakasham AP 

PROVIDER: S-EPMC9947987 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature