Ring-opening polymerization of lactides and ε-caprolactone catalyzed by Zn(II) aryl carboxylate complexes supported by 4-pyridinyl schiff base ligands.
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ABSTRACT: Synthesis and catalytic studies of aryl carboxylate Zn (II) complexes is reported. Reaction of substituted (E)-N-phenyl-1-(pyridin-4-yl)methanimine with a methanolic solution of Zn(CH3COO)2 and substituted aryl carboxylate co-ligands gave heteroleptic Zn(II) complexes; [Zn(C6H5COO)2(L1)]2 (1), [Zn(C7H7COO)2(L1)]2 (2), [Zn (4-F-C6H4COO)2(L1)]2 (3), [Zn(C6H5COO)2(L2)]2 (4), [Zn(C7H7COO)2(L2)]2 (5), [Zn (4-F-C6H4COO)2(L2)]2
SUBMITTER: Akintayo DC
PROVIDER: S-EPMC9950825 | biostudies-literature | 2023 Feb
REPOSITORIES: biostudies-literature
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