Experimental Band Structure of Pb(Zr,Ti)O₃ : Mechanism of Ferroelectric Stabilization.

ABSTRACT: Pb(Zr,Ti)O₃ (PZT) is the most common ferroelectric (FE) material widely used in solid-state technology. Despite intense studies of PZT over decades, its intrinsic band structure, electron energy depending on 3D momentum k, is still unknown. Here, Pb(Zr_0.2 Ti_0.8 )O₃ using soft-X-ray angle-resolved photoelectron spectroscopy (ARPES) is explored. The enhanced photoelectron escape depth in this photon energy range allows sharp intrinsic definition of the out-of-plane momentum k and thereby of the full 3D band structure. Furthermore, the problem of sample charging due to the inherently insulating nature of PZT is solved by using thin-film PZT samples, where a thickness-induced self-doping results in their heavy doping. For the first time, the soft-X-r

SUBMITTER: Popescu DG 

PROVIDER: S-EPMC9951575 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature