Nanoparticle Exsolution from Nanoporous Perovskites for Highly Active and Stable Catalysts.

ABSTRACT: Nanoporosity is clearly beneficial for the performance of heterogeneous catalysts. Although exsolution is a modern method to design innovative catalysts, thus far it is predominantly studied for sintered matrices. A quantitative description of the exsolution of Ni nanoparticles from nanoporous perovskite oxides and their effective application in the biogas dry reforming is here presented. The exsolution process is studied between 500 and 900 °C in nanoporous and sintered La_0.52 Sr_0.28 Ti_0.94 Ni_0.06 O_3±δ . Using temperature-programmed reduction (TPR) and X-ray absorption spectroscopy (XAS), it is shown that the faster and larger oxygen release in the nanoporous material is responsible for twice as high Ni reduction than in the sintered

SUBMITTER: Rudolph B 

PROVIDER: S-EPMC9951582 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature