Effect of Borate Cocatalysts toward Activity and Comonomer Incorporation in Ethylene Copolymerization by Half-Titanocene Catalysts in Methylcyclohexane.

ABSTRACT: Ethylene copolymerizations with 2-methyl-1-pentene, 1-dodecene (DD), vinylcyclohexane (VCH), [Me₂Si(C₅Me₄)(N ^t Bu)]TiCl₂ (1), Cp*TiMe₂(O-2,6- ⁱ Pr₂-4-RC₆H₂) [R = H (2), SiEt₃ (3)]-borate, and [A(H)]⁺[BAr₄]^- [Ar = C₆F₅; A(H)⁺ = N⁺(H)Me(n-C₁₈H₃₇)₂, N⁺(H)(CH₂CF₃)(n-C₁₈H₃₇)₂, HO⁺(n-C₁₄H₂₉)₂·O(n-C₁₄H₂₉)₂, HO⁺(n-C₁₆H₃₃)_2</

SUBMITTER: Kitphaitun S 

PROVIDER: S-EPMC9955119 | biostudies-literature | 2022 Oct

REPOSITORIES: biostudies-literature