Zinc-Mediated Allylation-Lactonization One-Pot Reaction to Methylene Butyrolactones: Renewable Monomers for Sustainable Acrylic Polymers with Closed-Loop Recyclability.

ABSTRACT: Despite biomass-derived methylene butyrolactone monomers having great potential in substituting the petroleum-based methacrylates for synthesizing the sustainable acrylic polymers, the possible industrial production of these cyclic monomers is unfortunately not practical due to moderate overall yields and harsh reaction conditions or a time-consuming multistep process. Here we report a convenient and effective synthetic approach to a series of biomass-derived methylene butyrolactone monomers via a zinc-mediated allylation-lactonization one-pot reaction of biorenewable aldehydes with ethyl 2-(bromomethyl)acrylate. Under simple room-temperature sonication conditions, near-quantitative conversions (>90%) can be accomplished within 5-30 min, providing pure products with high isolated yields of

SUBMITTER: Zhang ZH 

PROVIDER: S-EPMC9955236 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature