Assessing Recent Time-Dependent Double-Hybrid Density Functionals on Doublet-Doublet Excitations.

ABSTRACT: This work is the first thorough investigation of time-dependent double-hybrid density functionals (DHDFs) for the calculation of doublet-doublet excitation energies. It sheds light on the current state-of-the-art techniques in the field and clarifies if there is still room for future improvements. Overall, 29 hybrid functionals and DHDFs are investigated. We separately analyze the individual impacts of the Tamm-Dancoff approximation (TDA), range separation, and spin-component/opposite scaling (SCS/SOS) on 45 doublet-doublet excitations in 23 radicals before concluding with an overarching analysis that includes and excludes challenging excitations with double-excitation or multireference character. Our results show again that so-called "nonempirical" DHDFs are outperformed by semiempirical

SUBMITTER: Van Dijk J 

PROVIDER: S-EPMC9955292 | biostudies-literature | 2022 Sep

REPOSITORIES: biostudies-literature