Controlling the LCST-Phase Transition in Azobenzene-Functionalized Poly (N-Isopropylacrlyamide) Hydrogels by Light.

ABSTRACT: Poly(N-isopropylacrylamide) PNIPAAm hydrogels were modified with a new azobenzene-containing co-monomer. In this work, light responsiveness as an additional functionality, is conceptualized to induce two phase transitions in the same material, which can be controlled by light. For a hydrogel with merely 2.5 mol% of this co-monomer, the lower critical solution transition temperature (LCST) was lowered by 12 °C (to 20 °C) compared to PNIPAAm (LCST at 32 °C), as analyzed by differential scanning calorimetry (DSC). The untreated unimodal endotherm split into a bimodal peak upon irradiation with UV-light, giving a second onset due to the switched (Z) isomer-rich regions, LCST*_H2.5%-(Z) = 26 °C. On irradiation with 450 nm, leading to the r

SUBMITTER: Colaco R 

PROVIDER: S-EPMC9956105 | biostudies-literature | 2023 Jan

REPOSITORIES: biostudies-literature