Mid-infrared cross-comb spectroscopy.

ABSTRACT: Dual-comb spectroscopy has been proven beneficial in molecular characterization but remains challenging in the mid-infrared region due to difficulties in sources and efficient photodetection. Here we introduce cross-comb spectroscopy, in which a mid-infrared comb is upconverted via sum-frequency generation with a near-infrared comb of a shifted repetition rate and then interfered with a spectral extension of the near-infrared comb. We measure CO₂ absorption around 4.25 µm with a 1-µm photodetector, exhibiting a 233-cm^-1 instantaneous bandwidth, 28000 comb lines, a single-shot signal-to-noise ratio of 167 and a figure of merit of 2.4 × 10⁶ Hz^1/2. We show that cross-comb spectroscopy can have superior signal-to-noise ratio, sensitivity, dynamic ran

SUBMITTER: Liu M 

PROVIDER: S-EPMC9957991 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature