Self-Assembly of a Two-Dimensional Coordination Polymer Based on Silver and Lanthanide Tetrakis-Acylpyrazolonates: An Efficient New Strategy for Suppressing Ligand-to-Metal Charge Transfer Quenching of Europium Luminescence.

ABSTRACT: A new strategy for the easy polymerization of anionic [Ln(Q^cy)₄]^- (HQ^cy-4-(cyclohexanecarbonyl)-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one) into two-dimensional layers of [AgLn(Q^cy)₄]_n (Ln = Sm, Eu, Gd, Tb and Dy) is proposed by binding the single molecular anions [Ln(Q^cy)₄]^- to silver cations through the coordination of the pyridinic nitrogen atoms of the pyrazolonate rings. The luminescent properties of [AgLn(Q^cy)₄]_n have been studied in detail, and it was shown that the previously described low photoluminescence quantum yield (PLQY) of [Eu(Q^cy)₄]^- is due to Ligand-To-Metal Charge Transfer (LMCT) quenching, whi

SUBMITTER: Belousov YA 

PROVIDER: S-EPMC9960442 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature