Fast Recombination of Charge-Transfer State in Organic Photovoltaic Composite of P3HT and Semiconducting Carbon Nanotubes Is the Reason for Its Poor Photovoltaic Performance.

ABSTRACT: Although the photovoltaic performance of the composite of poly-3-hexylthiophene (P3HT) with semiconducting single-walled carbon nanotubes (s-SWCNT) is promising, the short-circuit current density j_SC is much lower than that for typical polymer/fullerene composites. Out-of-phase electron spin echo (ESE) technique with laser excitation of the P3HT/s-SWCNT composite was used to clarify the origin of the poor photogeneration of free charges. The appearance of out-of-phase ESE signal is a solid proof that the charge-transfer state of P3HT⁺/s-SWCNT^- is formed upon photoexcitation and the electron spins of P3HT⁺ and s-SWCNT^- are correlated. No out-of-phase ESE signal was detected in the same experiment with pristine P3HT film. The out-

SUBMITTER: Uvarov MN 

PROVIDER: S-EPMC9961616 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature