Synthesis of Disubstituted Carboxonium Derivatives of Closo-Decaborate Anion [2,6-B₁₀H₈O₂CC₆H₅]^-: Theoretical and Experimental Study.

ABSTRACT: A comprehensive study focused on the preparation of disubstituted carboxonium derivatives of closo-decaborate anion [2,6-B₁₀H₈O₂CC₆H₅]^- was carried out. The proposed synthesis of the target product was based on the interaction between the anion [B₁₀H₁₁]^- and benzoic acid C₆H₅COOH. It was shown that the formation of this product proceeds stepwise through the formation of a mono-substituted product [B₁₀H₉OC(OH)C₆H₅]^-. In addition, an alternative one-step approach for obtaining the target derivative is postulated. The structure of tetrabutylammonium salts of carboxonium derivative ((C₄H₉)

SUBMITTER: Klyukin IN 

PROVIDER: S-EPMC9966448 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature