Softness of hydrated salt crystals under deliquescence.

ABSTRACT: Deliquescence is a first-order phase transition, happening when a salt absorbs water vapor. This has a major impact on the stability of crystalline powders that are important for example in pharmacology, food science and for our environment and climate. Here we show that during deliquescence, the abundant salt sodium sulfate decahydrate, mirabilite (Na₂SO₄·10H₂O), behaves differently than anhydrous salts. Using various microscopy techniques combined with Raman spectroscopy, we show that mirabilite crystals not only lose their facets but also become soft and deformable. As a result, microcrystals of mirabilite simultaneously behave crystalline-like in the core bulk and liquid-like at the surface. Defects at the surface can heal at a speed much faster than th

SUBMITTER: Wijnhorst R 

PROVIDER: S-EPMC9968288 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature