Aromatic and aliphatic hydrocarbon hydroxylation via a formally Ni^IVO oxidant.

ABSTRACT: The reaction of (NMe₄)₂[Ni^II(L^Ph)(OAc)] (1[OAc], L^Ph = 2,2',2''-nitrilo-tris-(N-phenylacetamide); OAc = acetate) with 3-chloroperoxybenzoic acid (m-CPBA) resulted in the formation of a self-hydroxylated Ni^III-phenolate complex, 2, where one of the phenyl groups of L^Ph underwent hydroxylation. 2 was characterised by UV-Vis, EPR, and XAS spectroscopies and ESI-MS. 2 decayed to yield a previously characterised Ni^II-phenolate complex, 3. We postulate that self-hydroxylation was mediated by a formally Ni^IVO oxidant, formed from the reaction of 1[OAc] with m-CPBA, which undergoes electrophilic aromatic substitution to yield 2. This is supported by an analysis of the kinetic an

SUBMITTER: Heim P 

PROVIDER: S-EPMC9972353 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature