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ABSTRACT:
SUBMITTER: Kibler AJ
PROVIDER: S-EPMC9976276 | biostudies-literature | 2023 Feb
REPOSITORIES: biostudies-literature
Kibler Alexander J AJ Tsang Nicole N Winslow Max M Argent Stephen P SP Lam Hon Wai HW Robinson David D Newton Graham N GN
Inorganic chemistry 20230210 8
Organofunctionalization of polyoxometalates (POMs) allows the preparation of hybrid molecular systems with tunable electronic properties. Currently, there are only a handful of approaches that allow for the fine-tuning of POM frontier molecular orbitals in a predictable manner. Herein, we demonstrate a new functionalization method for the Wells-Dawson polyoxotungstate [P<sub>2</sub>W<sub>18</sub>O<sub>62</sub>]<sup>6-</sup> using arylarsonic acids which enables modulation of the redox and photoc ...[more]