Origin of the Unusual Ground-State Spin S = 9 in a Cr₁₀ Single-Molecule Magnet.

ABSTRACT: The molecular wheel [Cr₁₀(OMe)₂₀(O₂CCMe₃)₁₀], abbreviated {Cr₁₀}, with an unusual intermediate total spin S = 9 and non-negligible cluster anisotropy, D/k_B = -0.045(2) K, is a rare case among wheels based on an even number of 3d-metals, which usually present an antiferromagnetic (AF) ground state (S = 0). Herein, we unveil the origin of such a behavior. Angular magnetometry measurements performed on a single crystal confirmed the axial anisotropic behavior of {Cr₁₀}. For powder samples, the temperature dependence of the susceptibility plotted as χT(T) showed an overall ferromagnetic (FM) behavior down to 1.8 K, whereas the magnetization curve M(H)

SUBMITTER: Rubin J 

PROVIDER: S-EPMC9979690 | biostudies-literature | 2022 Jul

REPOSITORIES: biostudies-literature