Probing sub-5 Angstrom micropores in carbon for precise light olefin/paraffin separation.

ABSTRACT: Olefin/paraffin separation is an important but challenging and energy-intensive process in petrochemical industry. The realization of carbons with size-exclusion capability is highly desirable but rarely reported. Herein, we report polydopamine-derived carbons (PDA-Cx, where x refers to the pyrolysis temperature) with tailorable sub-5 Å micropore orifices together with larger microvoids by one-step pyrolysis. The sub-5 Å micropore orifices centered at 4.1-4.3 Å in PDA-C800 and 3.7-4.0 Å in PDA-C900 allow the entry of olefins while entirely excluding their paraffin counterparts, performing a precise cut-off to discriminate olefin/paraffin with sub-angstrom discrepancy. The larger voids enable high C₂H₄ and C₃H₆ capacities of 2.25 and 1.98 mmol g

SUBMITTER: Du S 

PROVIDER: S-EPMC9981619 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature