Inducing Nucleophilic Reactivity at Beryllium with an Aluminyl Ligand.

ABSTRACT: The reactions of anionic aluminium or gallium nucleophiles {K[E(NON)]}₂ (E = Al, 1; Ga, 2; NON = 4,5-bis(2,6-diisopropylanilido)-2,7-ditert-butyl-9,9-dimethylxanthene) with beryllocene (BeCp₂) led to the displacement of one cyclopentadienyl ligand at beryllium and the formation of compounds containing Be-Al or Be-Ga bonds (NON)EBeCp (E = Al, 3; Ga, 4). The Be-Al bond in the beryllium-aluminyl complex [2.310(4) Å] is much shorter than that found in the small number of previous examples [2.368(2) to 2.432(6) Å], and quantum chemical calculations suggest the existence of a non-nuclear attractor (NNA) for the Be-Al interaction. This represents the first example of a NNA for a heteroatomic interaction in an isolated molecular complex. As

SUBMITTER: Boronski JT 

PROVIDER: S-EPMC9983009 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature