Near-infrared absorbing acceptor with suppressed triplet exciton generation enabling high performance tandem organic solar cells.

ABSTRACT: Reducing the energy loss of sub-cells is critical for high performance tandem organic solar cells, while it is limited by the severe non-radiative voltage loss via the formation of non-emissive triplet excitons. Herein, we develop an ultra-narrow bandgap acceptor BTPSeV-4F through replacement of terminal thiophene by selenophene in the central fused ring of BTPSV-4F, for constructing efficient tandem organic solar cells. The selenophene substitution further decrease the optical bandgap of BTPSV-4F to 1.17 eV and suppress the formation of triplet exciton in the BTPSV-4F-based devices. The organic solar cells with BTPSeV-4F as acceptor demonstrate a higher power conversion efficiency of 14.2% with a record high short-circuit current density of 30.1 mA cm^-2 and low energy loss of 0

SUBMITTER: Jia Z 

PROVIDER: S-EPMC9985646 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature