Iridium oxide nanoribbons with metastable monoclinic phase for highly efficient electrocatalytic oxygen evolution.

ABSTRACT: Metastable metal oxides with ribbon morphologies have promising applications for energy conversion catalysis, however they are largely restricted by their limited synthesis methods. In this study, a monoclinic phase iridium oxide nanoribbon with a space group of C2/m is successfully obtained, which is distinct from rutile iridium oxide with a stable tetragonal phase (P42/mnm). A molten-alkali mechanochemical method provides a unique strategy for achieving this layered nanoribbon structure via a conversion from a monoclinic phase K_0.25IrO₂ (I2/m (12)) precursor. The formation mechanism of IrO₂ nanoribbon is clearly revealed, with its further conversion to IrO₂ nanosheet with a trigonal phase. When applied as an electrocatalyst for the oxygen evolution reaction in acidic condition, the intrinsic catalytic activity of IrO₂ nanoribbon is higher than that of tetragonal phase IrO₂ due to the low d band centre of Ir in this special monoclinic phase structure, as confirmed by density functional theory calculations.

SUBMITTER: Liao F 

PROVIDER: S-EPMC9985653 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature