Ni^II and Cu^II complexes of a salen ligand bearing ferrocenes in its secondary coordination sphere.

ABSTRACT: Herein, we report the synthesis, spectroscopic characterization and electrochemical investigation of the Ni^II and Cu^II complexes of a novel Sal ligand bearing two ferrocene moieties attached at its diimine linker, M(Sal)^Fc. The electronic spectra of M(Sal)^Fc are near identical to its phenyl-substituted counterpart, M(Sal)^Ph, indicating the ferrocene moieties exist in the secondary coordination sphere of M(Sal)^Fc. The cyclic voltammograms of M(Sal)^Fc exhibit an additional two-electron wave in comparison to M(Sal)^Ph, which is assigned to the sequential oxidation of the two ferrocene moieties. The chemical oxidation of M(Sal)^Fc, monitored by low temperature UV-vis spectroscopy, supports the form

SUBMITTER: Sailer R 

PROVIDER: S-EPMC9986886 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature