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Simultaneous precipitation and discharge plasma processing for one-step synthesis of α-Fe₂O₃-Fe₃O₄/graphene visible light magnetically separable photocatalysts.

ABSTRACT: A novel facile combination of precipitation and plasma discharge reaction is successfully employed for one-step synthesis of an α-Fe₂O₃-Fe₃O₄ graphene nanocomposite (GFs). The co-existence and anchoring of hematite (α-Fe₂O₃) and magnetite (Fe₃O₄) nanoparticles onto a graphene sheet in the as synthesized GFs were verified by results of XRD, Raman, SEM, TEM, and XPS. HRTEM characterization was used for confirming the bonding between α-Fe₂O₃/Fe₃O₄ nanoparticles and the graphene sheet. Consequently, GFs shows superior photodegrading performance towards methylene blue (MB), compared to individual α-Fe₂O₃/Fe₃O₄ nanoparticles, as a result of band gap narrowing and the electron-hole pair recombination rate reducing. Moreover, GFs allows a good possibility of separating and recycling under an external-magnetic field, suggesting potential in visible-light-promoted photocatalytic applications.

SUBMITTER: Tuyen NL

PROVIDER: S-EPMC9989846 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature

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Simultaneous precipitation and discharge plasma processing for one-step synthesis of α-Fe2O3-Fe3O4/graphene visible light magnetically separable photocatalysts.

Tuyen Nguyen Long NL Toan Tran Quoc TQ Hung Nguyen Ba NB Trieu Pham Quoc PQ Dinh Nguyen Ngoc NN Do Danh Bich DB Van Thanh Dang D Nguyen Van-Truong VT Nguyen Van-Truong VT

RSC advances 20230307 11

A novel facile combination of precipitation and plasma discharge reaction is successfully employed for one-step synthesis of an α-Fe2O3-Fe3O4 graphene nanocomposite (GFs). The co-existence and anchoring of hematite (α-Fe2O3) and magnetite (Fe3O4) nanoparticles onto a graphene sheet in the as synthesized GFs were verified by results of XRD, Raman, SEM, TEM, and XPS. HRTEM characterization was used for confirmi ...[more]

PMID: 36895775

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Project description:A series of magnetically separable rGO/Fe3O4 nanocomposites with various amounts of graphene oxide were successfully prepared by a simple ultrasonication assisted precipitation combined with a solvothermal method and their catalytic activity was evaluated for the selective liquid phase oxidation of cyclohexene using hydrogen peroxide as a green oxidant. The prepared materials were characterized using XRD, FTIR, FESEM, TEM, HRTEM, BET/BJH, XPS and VSM analysis. The presence of well crystallized Fe3O4 as the active iron species was seen in the crystal studies of the nanocomposites. The electron microscopy analysis indicated the fine surface dispersion of spherical Fe3O4 nanoparticles on the thin surface layers of partially-reduced graphene oxide (rGO) nanosheets. The decoration of Fe3O4 nanospheres on thin rGO layers was clearly observable in all of the nanocomposites. The XPS analysis was performed to evaluate the chemical states of the elements present in the samples. The surface area of the nanocomposites was increased significantly by increasing the amount of GO and the pore structures were effectively tuned by the amount of rGO in the nanocomposites. The magnetic saturation values of the nanocomposites were found to be sufficient for their efficient magnetic separation. The catalytic activity results show that the cyclohexene conversion reached 75.3% with a highest 1,2-cyclohexane diol selectivity of 81% over 5% rGO incorporated nanocomposite using H2O2 as the oxidant and acetonitrile as the solvent at 70 °C for 6 h. The reaction conditions were further optimized by changing the variables and a possible reaction mechanism was proposed. The enhanced catalytic activity of the nanocomposites for cyclohexene oxidation could be attributed to the fast accomplishment of the Fe2+/Fe3+ redox cycle in the composites due the sacrificial role of rGO and its synergistic effect with Fe3O4, originating from the conjugated network of π-electrons in its surface structure. The rapid and easy separation of the magnetic nanocomposites from the reaction mixture using an external magnet makes the present catalysts highly efficient for the reaction. Moreover, the catalyst retained its activity for five repeated runs without any drastic drop in the reactant conversion and product selectivity.

Dataset Information

Simultaneous precipitation and discharge plasma processing for one-step synthesis of α-Fe₂O₃-Fe₃O₄/graphene visible light magnetically separable photocatalysts.

Publications

Simultaneous precipitation and discharge plasma processing for one-step synthesis of α-Fe<sub>2</sub>O<sub>3</sub>-Fe<sub>3</sub>O<sub>4</sub>/graphene visible light magnetically separable photocatalysts.

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