Conjugated porphyrin polymer films with nickel single sites for the electrocatalytic oxygen evolution reaction.

ABSTRACT: Directly fused nickel(ii) porphyrins are successfully investigated as heterogeneous single-site catalysts for the oxygen evolution reaction (OER). Conjugated polymer thin films from Ni(ii) 5,15-(di-4-methoxycarbonylphenyl)porphyrin (pNiDCOOMePP) and Ni(ii) 5,15-diphenylporphyrin (pNiDPP) showed an OER onset overpotential of 270 mV, and current densities of 1.6 mA cm^-2 and 1.2 mA cm^-2 at 1.6 V vs. RHE, respectively, representing almost a hundred times higher activity than those of monomeric thin films. The fused porphyrin thin films are more kinetically and thermodynamically active than their non-polymerized counterparts mainly due to the formation of conjugated structures enabling a dinuclear radical oxo-coupling (ROC) mechanism at low overpotential. More impor

SUBMITTER: Bansal D 

PROVIDER: S-EPMC9990145 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature