Excited state energy landscape of phosphorescent group 14 complexes.

ABSTRACT: Great progress has been achieved on phosphorescent or photoactive complexes of the Earth-abundant transition metals, while examples for phosphorescent heavy main group element complexes are rare, in particular for group 14 complexes in the oxidation state +II. The known compounds often show only weak phosphorescence with fast non-radiative deactivation. The underlying photophysical processes and the nature of the phosphorescent electronic states have remained essentially unexplored. The present combined photophysical and theoretical study on tin(ii) and lead(ii) complexes E(bpep) with the dianionic tridentate ligand bpep^2- (E = Sn, Pb; H₂bpep = 2-[1,1-bis(1H-pyrrol-2-yl)ethyl]pyridine) provides unprecedented insight in the excited state energy landscape of tetr

SUBMITTER: Sikora P 

PROVIDER: S-EPMC9993841 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature