Orthogonal, modular anion-cation and cation-anion self-assembly using pre-programmed anion binding sites.

ABSTRACT: Subcomponent self-assembly relies on cation coordination whereas the roles of anions often only emerge during the assembly process. When sites for anions are instead pre-programmed, they have the potential to be used as orthogonal elements to build up structure in a predictable and modular way. We explore this idea by combining cation (M⁺) and anion (X^-) binding sites together and show the orthogonal and modular build up of structure in a multi-ion assembly. Cation binding is based on a ligand (L) made by subcomponent metal-imine chemistry (M⁺ = Cu⁺, Au⁺) while the site for anion binding (X^- = BF₄ ^-, ClO₄ ^-) derives from the inner cavity of cyanostar (CS) macrocycles. The two sites

SUBMITTER: Dhara A 

PROVIDER: S-EPMC9993851 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature