Structure and bonding patterns in heterometallic organometallics with linear Ln-Pd-Ln motifs.

ABSTRACT: Complexes with short intermetallic distances between transition metal fragments and lanthanide (Ln) fragments are fascinating objects of study, owing to the ambiguity of the nature of the interaction. The addition of the divalent lanthanide fragments Cp*₂Ln(OEt₂) (Ln = Sm or Yb) to a Pd(ii) complex bearing the deprotonated form of the redox-active, non-symmetrical ligand, 2-pyrimidin-2-yl-1H-benzimidazole (Hbimpm), leads to two isostructural complexes, of the general formula (Cp*₂Ln)₂[μ-Pd(pyridyl)₂] (Ln = Sm (4) and Yb (5)). These adducts have interesting features, such as unique linear Ln-Pd-Ln arrangements and short Ln-Pd distances, which deviate from the expected lanthanide contraction. A mixed computational and spectroscopi

SUBMITTER: Cemortan V 

PROVIDER: S-EPMC9993901 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature