Syntheses and crystal structures of bis-(4-methyl-pyridine-κN)bis-(seleno-cyanato-κN)zinc(II) and catena-poly[[bis-(4-methyl-pyridine-κN)cadmium(II)]-di-μ-seleno-cyanato-κ2 N:Se;κ2 Se:N].
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ABSTRACT: The reactions of Zn(NO3)2 .6H2O and Cd(NO3)2 .4H2O with KSeCN and 4-meth-yl-pyridine (C6H7N; 4-picoline) lead to the formation of crystals of bis-(4-methyl-pyridine-κN)bis-(seleno-cyanato-κN)zinc(II), [Cd(NCSe)2(C6H7N)2] (1), and catena-poly[[bis-(4-methyl-pyridine-κN)cadmium(II)]-di-μ-seleno-cyanato-κ2 N:Se;κ2 Se:N], [Cd(NCSe)2(C6H7N)2] n (2), suitable for single-crystal X-ray diffraction. The asymmetric unit of compound 1 consists of one Zn cation that is located on a twofold ro
SUBMITTER: Nather C
PROVIDER: S-EPMC9993905 | biostudies-literature | 2023 Feb
REPOSITORIES: biostudies-literature
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