Synthesis, crystal structure and Hirshfeld surface analysis of bis-[4-(2-amino-eth-yl)morpholine-κ² N,N']di-aqua-nickel(II) dichloride.

ABSTRACT: The title coordination compound, [Ni(C₆H₁₄N₂O)₂(H₂O)₂]Cl₂, was synthesized by mixing 4-(2-amino-eth-yl)morpholine and nickel chloride in double-distilled water. The asymmetric unit comprises one half of an Ni^II cation (located on an inversion centre), one 4-(2-amino-eth-yl)morpholine ligand, one coordinated water mol-ecule and one chloride ion outside the metal coordination sphere. The nickel ion is in a octa-hedral environment of the N₄O₂ type, coordinating four N atoms from two 4-(2-amino-eth-yl)morpholine ligands and two trans-located O atoms from two water mol-ecules. The morpholine ligand was found disordered over two positions with a site occupancy ratio of 0.708 (8):0

SUBMITTER: Chidambaranathan B 

PROVIDER: S-EPMC9993921 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature