Quantitative Investigation of the Rate of Intersystem Crossing in the Strong Exciton-Photon Coupling Regime.

ABSTRACT: Strong interactions between excitons and photons lead to the formation of exciton-polaritons, which possess completely different properties compared to their constituents. The polaritons are created by incorporating a material in an optical cavity where the electromagnetic field is tightly confined. Over the last few years, the relaxation of polaritonic states has been shown to enable a new kind of energy transfer event, which is efficient at length scales substantially larger than the typical Förster radius. However, the importance of such energy transfer depends on the ability of the short-lived polaritonic states to efficiently decay to molecular localized states that can perform a photochemical process, such as charge transfer or triplet states. Here, we investigate quantitatively the

SUBMITTER: Mukherjee A 

PROVIDER: S-EPMC9999416 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature