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Catena-Poly[[bis-[2-(2,3-dimethyl-anilino)benzoato-?O]cadmium(II)]-di-?-3-pyridylmethanol-?N:O;?O:N].


ABSTRACT: In the crystal structure of the title compound, [Cd(C(15)H(14)NO(2))(2)(C(6)H(7)NO)(2)](n), the Cd atom displays a distorted octa-hedral geometry, including two pyridine N atoms and two hydroxyl O from four symmetry-related 3-pyridylmethanol (3-pyme) ligands and two carboxylate O atoms from mefenamate [2-(2,3-dimethyl-anilino)benzoate] anions. The Cd atoms are connected via the bridging 3-pyme ligands into chains, that extend in the a-axis direction. The Cd atom is located on a center of inversion, whereas the 3-pyme ligands and the mefenamate anions occupy general positions.

SUBMITTER: Moncol J 

PROVIDER: S-EPMC2960823 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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catena-Poly[[bis-[2-(2,3-dimethyl-anilino)benzoato-κO]cadmium(II)]-di-μ-3-pyridylmethanol-κN:O;κO:N].

Moncol Jan J   Mikloš Dušan D   Segľa Peter P   Koman Marian M   Lis Tadeusz T  

Acta crystallographica. Section E, Structure reports online 20080206 Pt 3


In the crystal structure of the title compound, [Cd(C(15)H(14)NO(2))(2)(C(6)H(7)NO)(2)](n), the Cd atom displays a distorted octa-hedral geometry, including two pyridine N atoms and two hydroxyl O from four symmetry-related 3-pyridylmethanol (3-pyme) ligands and two carboxylate O atoms from mefenamate [2-(2,3-dimethyl-anilino)benzoate] anions. The Cd atoms are connected via the bridging 3-pyme ligands into chains, that extend in the a-axis direction. The Cd atom is located on a center of inversi  ...[more]

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