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Bis(4-fluoro-benzoato-?O,O')bis-(nicotinamide-?N)zinc(II) monohydrate.

ABSTRACT: The title compound, [Zn(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)]·H(2)O, is a monomeric complex. It contains two 4-fluoro-benzoate and two nicotinamide ligands and one uncoordinated water mol-ecule. The 4-fluoro-benzoates act as bidentate chelating ligands, while the nicotinamides are monodentate. The six-coordinate geometry around the Zn(II) atom may be described as highly distorted octa-hedral, with the two nicotinamide ligands arranged cis. Inter-molecular O-H?O and N-H?O hydrogen bonds link the mol-ecules into a supra-molecular structure.

SUBMITTER: Hokelek T

PROVIDER: S-EPMC2960841 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Bis(4-fluoro-benzoato-κO,O')bis-(nicotinamide-κN)zinc(II) monohydrate.

Hökelek Tuncer T Caylak Nagihan N Necefoğlu Hacali H

Acta crystallographica. Section E, Structure reports online 20080206 Pt 3

The title compound, [Zn(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)]·H(2)O, is a monomeric complex. It contains two 4-fluoro-benzoate and two nicotinamide ligands and one uncoordinated water mol-ecule. The 4-fluoro-benzoates act as bidentate chelating ligands, while the nicotinamides are monodentate. The six-coordinate geometry around the Zn(II) atom may be described as highly distorted octa-hedral, with the two nicotinamide ligands arranged cis. Inter-molecular O-H⋯O and N-H⋯O hydrogen bonds link the m ...[more]

PMID: 21201854

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