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Tetra-aqua-bis(1-hydr-oxy-2-naphthoato-?O)magnesium(II).

ABSTRACT: In the title mononuclear complex, [Mg(C(11)H(7)O(3))(2)(H(2)O)(4)], the Mg(II) atom is located on a centre of inversion and is coordinated by two O atoms from two 1-hydr-oxy-2-naphthoate ligands and four water mol-ecules in an octa-hedral geometry. The structure is consolidated by inter-molecular O-H?O hydrogen bonding, as well as by ?-? stacking inter-actions between adjacent naphthyl ring systems [centroid-centroid distance between parallel naphthoate rings is 3.768?(2)?Å].

SUBMITTER: Huang F 

PROVIDER: S-EPMC2960898 | biostudies-other | 2008

REPOSITORIES: biostudies-other

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Tetra-aqua-bis(1-hydr-oxy-2-naphthoato-κO)magnesium(II).

Huang Fu F   Song Wen-Dong WD  

Acta crystallographica. Section E, Structure reports online 20080314 Pt 4

In the title mononuclear complex, [Mg(C(11)H(7)O(3))(2)(H(2)O)(4)], the Mg(II) atom is located on a centre of inversion and is coordinated by two O atoms from two 1-hydr-oxy-2-naphthoate ligands and four water mol-ecules in an octa-hedral geometry. The structure is consolidated by inter-molecular O-H⋯O hydrogen bonding, as well as by π-π stacking inter-actions between adjacent naphthyl ring systems [centroid-centroid distance between parallel naphthoate rings is 3.768 (2) Å]. ...[more]