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Dibromido(2,3,9,10-tetra-methyl-1,4,8,11-tetra-azacyclo-tetra-deca-1,3,8,10-tetra-ene)cobalt(III) bromide.

ABSTRACT: In the title compound, [CoBr(2)(C(14)H(24)N(4))]·Br, the Co(III) ion is located on an inversion centre and possesses a distorted octa-hedral coordination geometry in which four nitro-gen donors of the ligand mol-ecule are in the equatorial plane and two Br(-) ions occupy both the axial sites to give a trans isomer. The Br(- )counter- anion is also located on an inversion centre.

SUBMITTER: El-Ghamry H 

PROVIDER: S-EPMC2971086 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Dibromido(2,3,9,10-tetra-methyl-1,4,8,11-tetra-azacyclo-tetra-deca-1,3,8,10-tetra-ene)cobalt(III) bromide.

El-Ghamry Hoda H   Issa Raafat R   El-Baradie Kamal K   Masaoka Shigeyuki S   Sakai Ken K  

Acta crystallographica. Section E, Structure reports online 20091017 Pt 11

In the title compound, [CoBr(2)(C(14)H(24)N(4))]·Br, the Co(III) ion is located on an inversion centre and possesses a distorted octa-hedral coordination geometry in which four nitro-gen donors of the ligand mol-ecule are in the equatorial plane and two Br(-) ions occupy both the axial sites to give a trans isomer. The Br(- )counter- anion is also located on an inversion centre. ...[more]