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Catena-Poly[[bis-[2-(1H-1,2,4-triazol-1-yl-?N)pyrazine]cadmium(II)]-di-?-thio-cyanato-?S:N;?N:S].

ABSTRACT: The title compound, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), is a coordination polymer with the Cd(II) centre located on a twofold rotation axis. The Cd(II) centre assumes a distorted octa-hedral geometry. The thio-cyanate anions function as bridging ligands between the Cd(II) centres, leading to a chain-like arrangement expanding along [001].

SUBMITTER: Li H 

PROVIDER: S-EPMC2977348 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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catena-Poly[[bis-[2-(1H-1,2,4-triazol-1-yl-κN)pyrazine]cadmium(II)]-di-μ-thio-cyanato-κS:N;κN:S].

Li Hong H   Xie Long Miao LM  

Acta crystallographica. Section E, Structure reports online 20090718 Pt 8

The title compound, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), is a coordination polymer with the Cd(II) centre located on a twofold rotation axis. The Cd(II) centre assumes a distorted octa-hedral geometry. The thio-cyanate anions function as bridging ligands between the Cd(II) centres, leading to a chain-like arrangement expanding along [001]. ...[more]