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[N'-(5-Bromo-2-oxidobenzyl-idene-?O)-3-hydr-oxy-2-naphthohydrazidato-?N',O]dicyclo-hexyl-tin(IV).

ABSTRACT: The environment at the Sn(IV) atom in the title compound, [Sn(C(6)H(11))(2)(C(18)H(11)BrN(2)O(3))], is distorted trigonal-bipyramidal, with the two cyclo-hexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97?(9)°. The presence of an intra-molecular O-H?N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure.

SUBMITTER: Lee SM 

PROVIDER: S-EPMC2979853 | biostudies-other | 2010 Jan

REPOSITORIES: biostudies-other

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[N'-(5-Bromo-2-oxidobenzyl-idene-κO)-3-hydr-oxy-2-naphthohydrazidato-κN',O]dicyclo-hexyl-tin(IV).

Lee See Mun SM   Mohd Ali Hapipah H   Lo Kong Mun KM  

Acta crystallographica. Section E, Structure reports online 20100116 Pt 2

The environment at the Sn(IV) atom in the title compound, [Sn(C(6)H(11))(2)(C(18)H(11)BrN(2)O(3))], is distorted trigonal-bipyramidal, with the two cyclo-hexyl groups and the imino N atom forming the equatorial plane. The axial O-Sn-O angle is 155.97 (9)°. The presence of an intra-molecular O-H⋯N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure. ...[more]