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2-(2-Fluoro-biphenyl-4-yl)-N'-(propan-2-yl-idene)propanohydrazide.


ABSTRACT: In the title compound, C(18)H(19)FN(2)O, the hydrazide side chain is approximately perpendicular to the central ring [dihedral angle = 76.80?(5)°]. The F atom is disordered over two positions with occupancies of 0.818?(2) and 0.182?(2). The packing consists of chains of mol-ecules parallel to the a axis, connected by a bifurcated N-H?(O,N) hydrogen bond and a weak C(phen-yl)-H?O hydrogen bond. The packing is extended to a layer structure parallel to the ab plane by a weak C(phen-yl)-H?F hydrogen bond.

SUBMITTER: Khanum S 

PROVIDER: S-EPMC2983908 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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2-(2-Fluoro-biphenyl-4-yl)-N'-(propan-2-yl-idene)propanohydrazide.

Khanum Saira S   Farman Muhammad M   Rama Nasim Hasan NH   Hameed Shahid S   Jones Peter G PG  

Acta crystallographica. Section E, Structure reports online 20100317 Pt 4


In the title compound, C(18)H(19)FN(2)O, the hydrazide side chain is approximately perpendicular to the central ring [dihedral angle = 76.80 (5)°]. The F atom is disordered over two positions with occupancies of 0.818 (2) and 0.182 (2). The packing consists of chains of mol-ecules parallel to the a axis, connected by a bifurcated N-H⋯(O,N) hydrogen bond and a weak C(phen-yl)-H⋯O hydrogen bond. The packing is extended to a layer structure parallel to the ab plane by a weak C(phen-yl)-H⋯F hydrogen  ...[more]