Mesit-yl(2,4,6-trimeth-oxy-phen-yl)borinic acid.

ABSTRACT: In the title mol-ecule, C(18)H(23)BO(4), the dihedral angle between the least-squares planes of the aromatic rings is 84.88?(3)°. The B atom deviates by 0.202?(1)?Å from the least-squares plane of the mesityl ring. All of the meth-oxy groups are approximately coplanar with the 2,4,6-trimeth-oxy-phenyl ring, whereas the BOH group is twisted with respect to it by 19.5°. The borinic OH group is engaged in an intra-molecular O-H?O hydrogen bond with one of ortho-meth-oxy groups. The mol-ecular structure is stabilized by weak C-H?O contacts. In the crystal, mol-ecules are linked by weak C-H?O and C-H?? inter-actions, generating a three-dimensional network.

SUBMITTER: Lulinski S 

PROVIDER: S-EPMC3006901 | biostudies-other | 2010

REPOSITORIES: biostudies-other