Ontology highlight
ABSTRACT:
SUBMITTER: Lee E
PROVIDER: S-EPMC3050425 | biostudies-other | 2010
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Structure reports online 20101224 Pt 1
The quaternary thio-phosphate, Cs(0.49)NbPS(6), caesium hexa-thio-niobiophosphate(V), has been synthesized by the reactive halide flux method. The title compound is isotypic with Rb(0.46)TaPS(6) and is made up of a bicapped trigonal-biprismatic [Nb(2)S(12)] unit and a tetra-hedral [PS(4)] group. The [Nb(2)S(12)] units linked by the [PS(4)] tetra-hedra form infinite chains, yielding a three-dimensional network with rather large van der Waals gaps along the c axis in which the disordered Cs(+) ion ...[more]