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Bis(?-3-chloro-benzene-1,2-dicarboxyl-ato-?O:O)bis-[diaqua-(5,5'-dimethyl-2,2'-bipyridine-?N,N')copper(II)].

ABSTRACT: In the centrosymmetric binuclear title compound, [Cu(2)(C(8)H(3)ClO(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(4)], the Cu(II) ion is six-coordinated by two N atoms from a 5,5'-dimethyl-2,2'-bipyridine ligand, two bridging O atoms from two 3-chloro-benzene-1,2-dicarboxyl-ate ligands and two water mol-ecules in a distorted octa-hedral geometry. The binuclear complex mol-ecules are linked together by inter-molecular O-H?O hydrogen bonds into a layer parallel to (100). The layers are connected by C-H?Cl hydrogen bonds. Intra-molecular O-H?O hydrogen bonds and ?-? inter-actions [centroid-centroid distance = 3.5958?(16)?Å] are also present.

SUBMITTER: Li FA 

PROVIDER: S-EPMC3201524 | biostudies-other | 2011 Oct

REPOSITORIES: biostudies-other

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Bis(μ-3-chloro-benzene-1,2-dicarboxyl-ato-κO:O)bis-[diaqua-(5,5'-dimethyl-2,2'-bipyridine-κN,N')copper(II)].

Li Fu-An FA   Xu Fu F   Hu Xiao-Ming XM  

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

In the centrosymmetric binuclear title compound, [Cu(2)(C(8)H(3)ClO(4))(2)(C(12)H(12)N(2))(2)(H(2)O)(4)], the Cu(II) ion is six-coordinated by two N atoms from a 5,5'-dimethyl-2,2'-bipyridine ligand, two bridging O atoms from two 3-chloro-benzene-1,2-dicarboxyl-ate ligands and two water mol-ecules in a distorted octa-hedral geometry. The binuclear complex mol-ecules are linked together by inter-molecular O-H⋯O hydrogen bonds into a layer parallel to (100). The layers are connected by C-H⋯Cl hydr  ...[more]