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Bis(piperazine-1,4-diium) hexa-chlorido-bismuthate(III) chloride monohydrate.

ABSTRACT: The crystal structure of the title compound, (C(4)H(12)N(2))(2)[BiCl(6)]Cl·H(2)O, consists of piperazinediium cations, [BiCl(6)](3-) anions, Cl(-) anions and uncoordinated water mol-ecules. The Bi(III) cation is coordinated by six Cl(-) anions in a slightly distorted octa-hedral geometry. The diprotonated piperazine ring adopts a chair conformation. In the crystal, extensive inter-molecular N-H?Cl, N-H?O and O-H?Cl hydrogen bonds occur.

SUBMITTER: Gao YH 

PROVIDER: S-EPMC3238614 | biostudies-other | 2011 Dec

REPOSITORIES: biostudies-other

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Bis(piperazine-1,4-diium) hexa-chlorido-bismuthate(III) chloride monohydrate.

Gao Yu-Hua YH   Liu Xiao-Jia XJ   Sun Lei L   Le Wen-Jun WJ  

Acta crystallographica. Section E, Structure reports online 20111105 Pt 12

The crystal structure of the title compound, (C(4)H(12)N(2))(2)[BiCl(6)]Cl·H(2)O, consists of piperazinediium cations, [BiCl(6)](3-) anions, Cl(-) anions and uncoordinated water mol-ecules. The Bi(III) cation is coordinated by six Cl(-) anions in a slightly distorted octa-hedral geometry. The diprotonated piperazine ring adopts a chair conformation. In the crystal, extensive inter-molecular N-H⋯Cl, N-H⋯O and O-H⋯Cl hydrogen bonds occur. ...[more]

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