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Bis{2,2'-[(2-amino-eth-yl)aza-nedi-yl]diethanaminium} di-?-sulfido-bis-(disulfido-germanate).

ABSTRACT: In the title compound, (C(6)H(20)N(4))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4-) anion is formed by two edge-sharing GeS(4) tetra-hedral units. The average terminal and bridging Ge-S bond lengths are 2.158?(14) and 2.276?(6)?Å, respectively. The anions and the diprotonated ammonium cations are organized into a three-dimensional network by N-H?S and N-H?N hydrogen bonds.

SUBMITTER: Xu C 

PROVIDER: S-EPMC3274887 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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Bis{2,2'-[(2-amino-eth-yl)aza-nedi-yl]diethanaminium} di-μ-sulfido-bis-(disulfido-germanate).

Xu Chao C   Zhang Jing-Jing JJ   Duan Taike T   Chen Qun Q   Zhang Qian-Feng QF  

Acta crystallographica. Section E, Structure reports online 20120114 Pt 2

In the title compound, (C(6)H(20)N(4))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4-) anion is formed by two edge-sharing GeS(4) tetra-hedral units. The average terminal and bridging Ge-S bond lengths are 2.158 (14) and 2.276 (6) Å, respectively. The anions and the diprotonated ammonium cations are organized into a three-dimensional network by N-H⋯S and N-H⋯N hydrogen bonds. ...[more]

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