Unknown

Dataset Information

0

Creatininium 2-chloro-acetate.

ABSTRACT: IN THE TITLE COMPOUND (SYSTEMATIC NAME: 2-amino-1-methyl-4-oxo-4,5-dihydro-1H-imidazol-3-ium 2-chloro-acetate), C(4)H(8)N(3)O(+)·C(2)H(2)ClO(2) (-), the mol-ecular aggregations are stabil-ized through classical (N-H?O) and non-classical (C-H?O and C-H?N) hydrogen-bonding inter-actions. The cations are linked to the anions, forming ion pairs through two N-H?O bonds that produce characteristic R(2) (2)(8) ring motifs. These cation-anion pairs are connected through another N-H?O hydrogen bond, leading to an R(4) (2)(8) ring motif. Further weak C-H?N inter-actions link the mol-ecules along the a axis, while other C-H?O inter-actions generate zigzag chains extending along b.

SUBMITTER: Ali AJ 

PROVIDER: S-EPMC3344436 | biostudies-other | 2012 May

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

Creatininium 2-chloro-acetate.

Ali A Jahubar AJ   Athimoolam S S   Bahadur S Asath SA  

Acta crystallographica. Section E, Structure reports online 20120404 Pt 5

<h4>In the title compound (systematic name</h4>2-amino-1-methyl-4-oxo-4,5-dihydro-1H-imidazol-3-ium 2-chloro-acetate), C(4)H(8)N(3)O(+)·C(2)H(2)ClO(2) (-), the mol-ecular aggregations are stabil-ized through classical (N-H⋯O) and non-classical (C-H⋯O and C-H⋯N) hydrogen-bonding inter-actions. The cations are linked to the anions, forming ion pairs through two N-H⋯O bonds that produce characteristic R(2) (2)(8) ring motifs. These cation-anion pairs are connected through another N-H⋯O hydrogen bon  ...[more]