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N'-[(E)-2-Hy-droxy-5-meth-oxy-benzyl-idene]-2-meth-oxy-benzohydrazide.

ABSTRACT: The mol-ecule of the title compound, C16H16N2O4, adopts an E conformation about the azomethine C=N double bond. The dihedral angle formed by the benzene rings is 18.88?(9)°. The mol-ecular conformation is stabilized by an intra-molecular O-H?N hydrogen bond, which forms an S(6) ring. In the crystal, the mol-ecules are linked into chains parallel to [001] by N-H?O hydrogen bonds. The chains are further connected into a three-dimensional network by ?-? stacking inter-actions with centroid-centroid distances of 3.6538?(10) and 3.8995?(11)?Å.

SUBMITTER: Baharudin MS 

PROVIDER: S-EPMC3588809 | biostudies-other | 2012 Dec

REPOSITORIES: biostudies-other

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N'-[(E)-2-Hy-droxy-5-meth-oxy-benzyl-idene]-2-meth-oxy-benzohydrazide.

Baharudin M Syukri MS   Taha Muhammad M   Ismail Nor Hadiani NH   Shah Syed Adnan Ali SA   Yousuf Sammer S  

Acta crystallographica. Section E, Structure reports online 20121103 Pt 12

The mol-ecule of the title compound, C16H16N2O4, adopts an E conformation about the azomethine C=N double bond. The dihedral angle formed by the benzene rings is 18.88 (9)°. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond, which forms an S(6) ring. In the crystal, the mol-ecules are linked into chains parallel to [001] by N-H⋯O hydrogen bonds. The chains are further connected into a three-dimensional network by π-π stacking inter-actions with centroid-centroid  ...[more]

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