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(S)-?-Benzyl-prolinium cis-[(S)-?-benzyl-prolinato]dichloridopalladium(II).

ABSTRACT: The title complex salt, (C12H16NO2)[PdCl2(C12H14NO2)], is of inter-est with respect to organic and organometallic catalysis. The compound crystallizes as very small orange-red irregular prisms and the asymmetric unit contains three crystallographically distinct cation-anion pairs. The coordination geometry about the palladium atoms is square-planar with the chloride ligands cis to one another. The structure displays N-H?Cl and O-H?O hydrogen bonding such that the N-H?Cl hydrogen bonds align the cation-anion pairs in a linear fashion along [001], with the O-H?O hydrogen bonds connecting these linear strands along [100] and [010].

SUBMITTER: Hobart DB 

PROVIDER: S-EPMC3647805 | biostudies-other | 2013 May

REPOSITORIES: biostudies-other

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(S)-α-Benzyl-prolinium cis-[(S)-α-benzyl-prolinato]dichloridopalladium(II).

Hobart David B DB   Hobart David B DB   Merola Joseph S JS  

Acta crystallographica. Section E, Structure reports online 20130413 Pt 5

The title complex salt, (C12H16NO2)[PdCl2(C12H14NO2)], is of inter-est with respect to organic and organometallic catalysis. The compound crystallizes as very small orange-red irregular prisms and the asymmetric unit contains three crystallographically distinct cation-anion pairs. The coordination geometry about the palladium atoms is square-planar with the chloride ligands cis to one another. The structure displays N-H⋯Cl and O-H⋯O hydrogen bonding such that the N-H⋯Cl hydrogen bonds align the  ...[more]