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Crystal structure of tri-phenyl(vinyl)-phospho-nium tetra-phenyl-borate.

ABSTRACT: The title ionic salt, C21H20P(+)·C24H20B(-), crystallized with two independent vinyl-tri-phenyl-phospho-nium cations and two independent tetra-phenyl-borate anions per asymmetric unit. These four independent moieties contain nearly perfect tetra-hedral symmetry about their respective central C atoms. In the crystal, there are no ?-stacking or other inter-molecular inter-actions present.

SUBMITTER: Bradfield JL 

PROVIDER: S-EPMC4257183 | biostudies-other | 2014 Oct

REPOSITORIES: biostudies-other

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Crystal structure of tri-phenyl(vinyl)-phospho-nium tetra-phenyl-borate.

Bradfield Joseph L JL   Braun Richard A RA   White Frankie F   Hendrich Jeffrey M JM   Sykora Richard E RE   Mirjafari Arsalan A  

Acta crystallographica. Section E, Structure reports online 20140930 Pt 10

The title ionic salt, C21H20P(+)·C24H20B(-), crystallized with two independent vinyl-tri-phenyl-phospho-nium cations and two independent tetra-phenyl-borate anions per asymmetric unit. These four independent moieties contain nearly perfect tetra-hedral symmetry about their respective central C atoms. In the crystal, there are no π-stacking or other inter-molecular inter-actions present. ...[more]