Strong, spectrally-tunable chirality in diffractive metasurfaces.
Ontology highlight
ABSTRACT: Metamaterials and metasurfaces provide a paradigm-changing approach for manipulating light. Their potential has been evinced by recent demonstrations of chiral responses much greater than those of natural materials. Here, we demonstrate theoretically and experimentally that the extrinsic chiral response of a metasurface can be dramatically enhanced by near-field diffraction effects. At the core of this phenomenon are lattice plasmon modes that respond selectively to the illumination's polarization handedness. The metasurface exhibits sharp features in its circular dichroism spectra, which are tunable over a broad bandwidth by changing the illumination angle over a few degrees. Using this property, we demonstrate an ultra-thin circular-polarization sensitive spectral filter with a linewidth of ~10 nm, which can be dynamically tuned over a spectral range of 200 nm. Chiral diffractive metasurfaces, such as the one proposed here, open exciting possibilities for ultra-thin photonic devices with tunable, spin-controlled functionality.
Project description:Chirality prevails in nature and is of great value for molecular biology, medicine, and bioscience. Due to the enhancement of chiroptical responses, chiral metasurfaces has attracted enormous attentions. In this paper, some novel polarization-sensitive transmission effects in terahertz chiral metasurfaces are exhibited. In the chiral metasurfaces whose unit cell consists of two basic resonators - a wire and a split ring resonator (SRR), we observe the asymmetrical transmission for circularly polarized state from the circular cross-polarization conversion spectra and the circular conversion dichroism (CCD). More importantly, we verify that the chiroptical activities can be affected by the coupling between the two resonators by simply moving their relative position in the terahertz metasurfaces. From the experimental and simulated results, we observe the distinguished variation in the circular cross-polarization conversion spectra and CCD, and combining with the theoretical analysis using coupled mode theory, we reveal that the chirality of the metasurfaces is strongly correlated to the coupling between the two modes determined by the wire and SRR. Finally, we demonstrate the coupling-enabled chirality by investigating the dependence of CCD on the coupling discrepancy with different relative positions of the two resonators. These findings offer the insights into the relationship between chirality and mode coupling and provide a theoretical method to design chiral metasurfaces and enhance the circular conversion dichroism, which have potential applications in the fields such as optical sensing, polarization imaging, and biological/chemical detection.
Project description:Recent attempts to synthesize hybrid perovskites with large chirality have been hampered by large size mismatch and weak interaction between their structure and the wavelength of light. Here we adopt a planar nanostructure design to overcome these limitations and realize all-dielectric perovskite metasurfaces with giant superstructural chirality. We identify a direct spectral correspondence between the near- and the far- field chirality, and tune the electric and magnetic multipole moments of the resonant chiral metamolecules to obtain large anisotropy factor of 0.49 and circular dichroism of 6350 mdeg. Simulations show that larger area metasurfaces could yield even higher optical activity, approaching the theoretical limits. Our results clearly demonstrate the advantages of nanostructrure engineering for the implementation of perovskite chiral photonic, optoelectronic, and spintronic devices.
Project description:Drug delivery with precise spatial and temporal control is of broad current interest in biology and medicine. Despite recent advances achieved by combining drugs or drug carriers with NIR light responsive plasmonic nanomaterials, existing technologies are not capable of preventing drug leakage or degradation. We report a new class of monodisperse gold nanocontainer that can stably encapsulate cargo molecules, yet is compact in size and tunable in spectral responses.
Project description:Actively controlling the polarization states of terahertz (THz) waves is essential for polarization-sensitive spectroscopy, which has various applications in anisotropy imaging, noncontact Hall measurement, and vibrational circular dichroism. In the THz regime, the lack of a polarization modulator hinders the development of this spectroscopy. We theoretically and experimentally demonstrate that conjugated bilayer chiral metamaterials (CMMs) integrated with Ge2Sb2Te5 (GST225) active components can achieve nonvolatile and continuously tunable optical activity in the THz region. A THz time-domain spectroscopic system was used to characterize the device, showing a tunable ellipticity (from ‒36° to 0°) and rotation of the plane polarization (from 32° to 0°) at approximately 0.73 THz by varying the GST225 state from amorphous (AM) to crystalline (CR). Moreover, a continuously tunable chiroptical response was experimentally observed by partially crystallizing the GST225, which can create intermediate states, having regions of both AM and CR states. Note that the GST225 has an advantage of nonvolatility over the other active elements and does not require any energy to retain its structural state. Our work allows the development of THz metadevices capable of actively manipulating the polarization of THz waves and may find applications for dynamically tunable THz circular polarizers and polarization modulators for THz emissions.
Project description:Highly efficient Metamaterials are necessary for applications in sensing, communication, etc. Fano resonance and electromagnetically induced transparency-like phenomena are essential for obtaining high Q-factor and sensitive Metamaterials. Employing both numerical simulations and experimental analysis, we investigate the emergence of Fano resonance in cross-resonator Metamaterials facilitated by the conductive coupling between dark and bright resonators. We analyze the gradual shift of the fano resonance by tuning the dark resonator and finally form an electromagnetically induced transparency-like transmission peak. The strong coupling of the resonator is observed in the form of an anti-crossing and discussed through analytical models. We demonstrate that the coupling strength of the dark and bright resonance in our metamaterial is proportional to the asymmetry parameter, albeit at the cost of the Fano resonance's Q-factor. The findings and methods introduced in this study can be used to develop highly efficient THz Metamaterials for various applications operable in room conditions.
Project description:Active control of strong chiroptical responses in metasurfaces can offer new opportunities for optical polarization engineering. Plasmonic active chiral metasurfaces have been investigated before, but their tunable chiroptical responses is limited due to inherent loss of plasmonic resonances, thus stimulating research in low loss active dielectric chiral metasurfaces. Among diverse tuning methods, electrically tunable dielectric chiral metasurfaces are promising thanks to their potential for on-chip integration. Here, we experimentally demonstrate nano-electromechanically tunable dielectric chiral metasurfaces with reflective circular dichroism (CD). We show a difference between absolute reflection under circulary polarized incident light with orthogonal polarization of over 0.85 in simulation and over 0.45 experimentally. The devices enable continuous control of CD by induced electrostatic forces from 0.45 to 0.01 with an electrical bias of 3V. This work highlights the potential of nano-electromechanically tunable metasurfaces for scalable optical polarization modulators.
Project description:This communication describes the first uncaging of stimuli in the far red, wavelengths that have much less of an adverse affect on cellular systems, via photolysis of photosensitized nanocapsules.
Project description:Chirality is a nearly ubiquitous natural phenomenon. Its minute presence in most naturally occurring materials makes it incredibly difficult to detect. Recent advances in metasurfaces indicate that they exhibit devisable chirality in novel forms; this finding offers an effective opening for studying chirality and its features in such nanostructures. These metasurfaces display vast possibilities for highly sensitive chirality discrimination in biological and chemical systems. Here, we show that two-layer metasurfaces based on twisted nanorods can generate giant spin-selective transmission and support engineered chirality in the near-infrared region. Two designed metasurfaces with opposite spin-selective transmission are proposed for treatment as enantiomers and can be used widely for spin selection and enhanced chiral sensing. Specifically, we demonstrate that the chirality in these proposed metasurfaces can be adjusted effectively by simply changing the orientation angle between the twisted nanorods. Our results offer simple and straightforward rules for chirality engineering in metasurfaces and suggest intriguing possibilities for the applications of such metasurfaces in spin optics and chiral sensing.
Project description:Current studies of biological tissues require visualizing diverse cell types and molecular interactions, creating a growing need for versatile techniques to simultaneously probe numerous targets. Traditional multiplexed imaging is limited to around five targets at once. Emerging methods using sequential rounds of staining, imaging, and signal removal can probe tens of targets but require specialized hardware and time-consuming workflows and face challenges with sample distortion and artifacts. We present a highly multiplexed fluorescence microscopy method using semiconducting polymer dots (Pdots) in a single round of staining and imaging. Pdots are small, bright, and photostable fluorescent probes with a wide range of tunable Stokes shifts (20 to 450 nanometers). Multiple series of Pdots with varying excitation wavelengths allow for fast (<1 minute) and single-round imaging of up to 21 targets in the brain and kidney. This method is based on a simple immunofluorescence workflow, efficient use of spectral space, standard hardware, and straightforward analysis, making it widely applicable for bioimaging laboratories.
Project description:Dynamic control over the polarization of light is highly desirable in many optical applications, including optical communications, laser science, three-dimensional displays, among others. Conventional methods for polarization control are often based on bulky optical elements. To achieve highly integrated optical devices, metasurfaces, which have been intensively studied in recent years, hold great promises to replace conventional optical elements for a variety of optical functions. In this work, we demonstrate electrically tunable optical metasurfaces for dynamic polarization conversion at visible frequencies. By exploring both the geometric and propagation phase tuning capabilities, rapid and reversible polarization rotation up to 90° is achieved for linearly polarized light. The dynamic functionality is imparted by liquid crystals, which serve as a thin surrounding medium with electrically tunable refractive indices for the metasurface antennas. Furthermore, we expand our concept to demonstrate electrically tunable metasurfaces for dynamic holography and holographic information generation with independently controlled multiple pixels.